Bis(methanol-κO)dioxido[3,3'-(1H-1,2,4-triazole-3,5-diyl)diphenolato-κ3O,N4,O']uranium(VI) methanol monosolvate.
In: Acta crystallographica. Section C, Crystal structure communications, Jg. 68 (2012-03-01), Heft Pt 3, S. m61-3
academicJournal
Zugriff:
The structure of the title compound, [U(C(14)H(9)N(3)O(2))O(2)(CH(3)OH)(2)]·CH(3)OH, is the first to be reported for an actinide complex including triazole ligands. The U(VI) atom exhibits a pentagonal-bipyramidal NO(6) coordination environment, involving two axial oxide ligands [U=O = 1.766 (3) and 1.789 (3) Å], four equatorial O atoms [U-O = 2.269 (3)-2.448 (3) Å] from the ligand and the two coordinated methanol molecules, and one equatorial N atom [U-N = 2.513 (4) Å] from the ligand. In the crystal structure, the complex molecules are linked via intermolecular N-H...O and O-H...O hydrogen bonds to form a two-dimensional structure.
Titel: |
Bis(methanol-κO)dioxido[3,3'-(1H-1,2,4-triazole-3,5-diyl)diphenolato-κ3O,N4,O']uranium(VI) methanol monosolvate.
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Autor/in / Beteiligte Person: | Raspertova, I ; Doroschuk, R ; Khomenko, D ; Lampeka, R |
Zeitschrift: | Acta crystallographica. Section C, Crystal structure communications, Jg. 68 (2012-03-01), Heft Pt 3, S. m61-3 |
Veröffentlichung: | <2008- > : Malden, MA : Wiley-Blackwell ; <i>Original Publication</i>: Copenhagen : Published for the International Union of Crystallography by Munksgaard, c1983-, 2012 |
Medientyp: | academicJournal |
ISSN: | 1600-5759 (electronic) |
DOI: | 10.1107/S0108270112003034 |
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