Electrochemical polymerization of fullerene in organic solvents
In: Proceedings of the III International Conference on Electronic Processes in Organic Materials, Kharkiv, Ukraine, 22-28 May, 2000Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals 361:275-280; Jg. 361 (2001) S. 275-280
Konferenz
- print, 10 ref
Zugriff:
The new method of fullerene polymerization initiated by electrolysis of C60 toluene-DMFA solutions in the presence of supporting electrolytes at stationary or rotating Pt, graphite, stainless steel electrodes have proposed. Formation of insoluble in toluene polyfullerene suspension is observed during the electrolysis at the fixed potential which is similar to the third wave of fullerene reduction. The suspension may be deposited on the transparent ITO electrodes or silicon substrate for producing the fullerene-based nanostructures, According to scanning electron microscopy the polymeric form of C60 consist a piece of films and the linear particles, which have a length about 100 μm. Mechanism of polymerization includes the anion - radical initiating particles (C60n-)* formation followed by the consequential reduction of C60.
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Electrochemical polymerization of fullerene in organic solvents
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| Autor/in / Beteiligte Person: | AKSIMENTYEVA, Olena I ; VOVK, Oleh M ; KRAVCHENKO, Yuriy G ; BODNARYUK-LUPSHAK, Natalya |
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| Quelle: | Proceedings of the III International Conference on Electronic Processes in Organic Materials, Kharkiv, Ukraine, 22-28 May, 2000Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals 361:275-280; Jg. 361 (2001) S. 275-280 |
| Veröffentlichung: | Philadelphia, PA: Gordon and Breach, 2001 |
| Medientyp: | Konferenz |
| Umfang: | print, 10 ref |
| ISSN: | 1058-725X (print) |
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