Electrochemical behavior of partially-discharged LixV2O5 electrodes upon interruption of current
In: Russian journal of electrochemistry, Jg. 38 (2002), Heft 9, S. 1004-1008
Online
academicJournal
- print, 6 ref
Zugriff:
A mathematical diffusion model, which takes into account the electrochemical behavior of partially-discharged thin-layer electrodes made of intercalation materials upon interruption of circuit, is put forward. The applicability of the model is tested by the example of LixV2O5 films. According to theoretical calculations and experimental data, the equilibrium potential of the films studied depends practically linearly on the degree of intercalation with a slope of -0.8 V for intercalation degrees of 0.3-0.7. The chemical diffusion coefficient of lithium in the films is equal to 1.5 x 10-11 cm2/s and changes insignificantly at these intercalation degrees.
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Electrochemical behavior of partially-discharged LixV2O5 electrodes upon interruption of current
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Autor/in / Beteiligte Person: | TYSYACHNYI, V. P ; SHEMBEL', E. M ; APOSTOLOVA, P. D |
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Zeitschrift: | Russian journal of electrochemistry, Jg. 38 (2002), Heft 9, S. 1004-1008 |
Veröffentlichung: | Birmingham, AL; Moscow: Interperiodica, 2002 |
Medientyp: | academicJournal |
Umfang: | print, 6 ref |
ISSN: | 1023-1935 (print) |
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